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Basic organometallic chemistry : containing comprehensive by Ionel Haiduc

By Ionel Haiduc

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Ergänzungsbände (New Supplement Series): Vol. 2/3. Organovanadium Compounds. Organochromium Compounds (1971, 1973). Vol. 4. Transuranium Elements. Part C. The Compounds (1972) (includes organometallic derivatives). Vol. 5. Organocobalt Compounds. Part I. Mononuclear Compounds (1973). Vol. 6. Organocobalt Compounds. Part II. Polynuclear Compounds (1973). 9. Perfluorohalogenoorgano Compounds of Main-Group Elements. P a r t i . Compounds of Sulfur (1973). Vol. 10/11. Organozirconium Compounds, Organohafnium Compounds (1973).

Organoiron Compounds. C4. Binuclear Compounds 4(1981). Organoiron Compounds. C5. Binuclear Compounds 5 (1981). Organocopper Compounds. Part 2 (1983) Organogold Compounds (1980). Organotitanium Compounds. Part 2 (1980). Organoantimony Compounds. Part 1 (1981), Part 2 (1981), Part 3 (1982). Uranium Ε 2. Coordination Compounds (including Organouranium Compounds) (1980). Organoantimony Compounds. Part 1. Compounds of Trivalent Antimony with Three S b - C Bonds (1981). Perfluorhalogeno Compounds of the Main-Group Elements.

Perhaps a three-carbon species based upon a C 3 B 9 cluster would be stable in a cationic form, C 3 B 9 H f2> but so far such compounds have not been reported. Delocalized bonds are also found in polynuclear metal carbonyl structures, and in other cluster-type organometallic compounds (see Chapter 11) in which metal atoms form polynuclear molecules via metal-metal bonding, sometimes with participation of 18 2. The Metal-Carbon Bond carbon atoms. Transition metal bonding in polynuclear species is more complex because of the participation of d-orbitals in the formation of the delocalized electronic system.

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