Chemistry

Adsorption at interfaces : papers from a symposium honoring by K L Mittal; Robert D Vold; Marjorie J Vold; American

By K L Mittal; Robert D Vold; Marjorie J Vold; American Chemical Society. Division of Colloid and Surface Chemistry.; American Chemical Society. Meeting (ed.)

Refereed and edited papers at the most modern advancements within the thought and purposes of curves and surfaces Thermodynamics of adsorption and interparticle forces / D.H. Everett and C.J. Radke -- Configurational habit of remoted chain molecules adsorbed from athermal suggestions / M. Lal, M.A. Turpin, K.A. Richardson, and D. Spencer -- Equilibrium movie strain on a flat, low-energy good / Robert J. stable -- Binding of solute and solvent on the interface and the gibbs floor extra / D.K. Chattoraj and S.P. Moulik -- Mechanism of sulfonate adsorption on the silver iodide-solution interface / ok. Osseo-Asare, D.W. Fuerstenau, and R.H. Ottewill -- Adsorption of dyes on water-swollen and non-swelling stable substrates / S.R. Sivaraja Iyer, A.S. Chanekar, and G. Srinivasan -- Adsorption of polystyrene on graphon from toluene / Victor okay. Dunn and Robert D. Vold -- Adsorption of ionic surfactants to porous glass : the exclusion of micelles and different solutes from adsorbed layers and the matter of adsorption maxima / Pasupati Mukerjee and Aroonsri Anavil -- DTA examine of water in porous glass / Chaur-Sun Ling and W. Drost-Hansen -- Monolayer reviews. five, Styrene-acrylic acid movies on aqueous substrates / Erwin Sheppard and Noubar Tcheurekdjian -- interplay of calcium ions with the combined monolayers of stearic acid and stearyl alcohol at pH 8.8 / D.O. Shah -- touch angles in Newton-Black cleaning soap motion pictures drawn from suggestions containing sodium dodecyl sulphate and electrolyte / J.A. De Feijter and A. Vrij -- Stratification in unfastened liquid movies / J.W. Keuskamp and J. Lyklema -- floor chemical houses of hugely fluorinated polymers / Marianne okay. Bernett and W.A. Zisman -- impact of floor oxygen complexes on floor habit of carbons / Balwant Rai Puri -- floor homes of nickel hydroxide prior to and after dehydration to nickel oxide / M. subject, F.J. Micale, C.L. Cronan, H. Leidheiser, Jr., and A.C. Zettlemoyer -- The size of low interfacial pressure through the spinning drop method / J.L. Cayias, R.S. Schechter, and W.H. Wade -- Adhesion of ice frozen from dilute electrolyte ideas / H.H.G. Jellinek -- Mechanism of olfaction defined utilizing interfacial stress measurements / D. V. Rathnamma -- function of double interactions and spreading strain in particulate soil elimination / Hermann Lange

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Additional info for Adsorption at interfaces : papers from a symposium honoring Robert D. Vold and Marjorie J. Vold sponsored by the Division of Colloid and Surface Chemistry at the 167th meeting of the American Chemical Society, Los Angeles, Calif., April 2-5, 1974

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The surface rehenate species is always isolated and possesses three terminal Re=O bonds and one bridging Re–O support bond. 5 Structure of dehydrated isolated surface monoxo ReO4 species inorganic coordination chemistry of rhenium oxide (preference for isolated ReO4 units with three Re=O bonds and one Re–O bond). 5 Molybdenum (+6) oxides Bulk polymolybdate chains usually contain MoO6 coordinated groups, which is unlike the polyvanadate and polychromate chains that are composed of VO4 and CrO4 units, respectively [60].

Like niobia, tantala can also exhibit TaO7 and TaO8 coordination. 7, made up of distorted TaO6 groups. Bulk Ta2 O5 exhibits a phase transition at 1360◦ C and the stable phases below and above this temperature are referred to as L–Ta2 O5 and H–Ta2 O5 , respectively. Poorly crystalline Ta2 O5 is present below ∼800◦ C and is present as Ta2 O5 ·nH2 O (tantalum oxhydrate). Both the L–Ta2 O5 and H–Ta2 O5 crystalline phases consist of a three-dimensional network of distorted TaO6 and TaO7 units. The vibrational spectra of gaseous Ta oxyhalide complexes have not been reported in the literature [61,62].

2 Vanadium (+5) oxides The bulk structural inorganic chemistry of vanadium (+5) oxides is the most varied among the bulk metal oxides, and has been determined from extensive x-ray crystallographic studies [60]. Bulk VO4 vanadate ions consist of isol4− ated (VO3− 4 orthovandate), dimeric (V2 O7 pyrovanadate) or polymeric chain ((VO3 )n− n metavanadate) structures. , Na3 VO4 , Na4 V2 O7 , and Nan (VO3 )n ). Bulk VO6 “DK3029_C001” — 2005/7/9 — 00:00 — page 8 — #8 Molecular Structures of Surface Metal Oxide Species 9 vanadates are also very common structures, and are typically found in extended vanadia structures.

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